Team Captains
Every season since the team was founded in 2001, the D.C. Divas have chosen team captains to lead them on the field. Captains serve as team leaders and represent the Divas at midfield for the opening coin toss at the start of each game.
Here is the full list of Divas players that have been chosen by their teammates to serve as team captains.
| Season | Team Captain(s) |
| 2001 | Brooke Hargrove, Amy Juang, Luann Peterson, Ivy Tillman, Deb Troell |
| 2002 | Alison Fischer, Brooke Hargrove, Amy Juang, Ivy Tillman, Deb Troell |
| 2003 | Gayle Dilla, Allyson Hamlin, Tessa Nelson, Ivy Tillman, Donna Wilkinson |
| 2004 | Gayle Dilla, Allyson Hamlin, Vickie Lucas, Ivy Tillman, Donna Wilkinson |
| 2005 | Gayle Dilla, Allyson Hamlin, Kathryn Hemlock, Vickie Lucas, Ivy Tillman |
| 2006 | Allyson Hamlin, Kathryn Hemlock, Vickie Lucas, Raynette Savoy, Ivy Tillman, Nikki Williams |
| 2007 | Alison Fischer, Allyson Hamlin, Vickie Lucas, Rachelle Pecovsky, Ivy Tillman, Nikki Williams |
| 2008 | Allyson Hamlin, Labelle Hillgrove, Vickie Lucas, Allysea Marfull, Ivy Tillman |
| 2009 | Allyson Hamlin, Labelle Hillgrove, Vickie Lucas, Allysea Marfull, Ivy Tillman, Nikki Williams |
| 2010 | Kathryn Hemlock, Amy Juang, Tara Stephenson |
| 2011 | Alison Fischer, Kenyetta Grigsby, Allyson Hamlin, T.K. Washington |
| 2012 | Callie Brownson, Allyson Hamlin, Tara Stephenson |
| 2013 | Callie Brownson, Allyson Hamlin, Trigger McNair |
| 2014 | Missy Bedwell, Callie Brownson, Allyson Hamlin, Rachel Huhn, Trigger McNair |
| 2015 | Missy Bedwell, Kenyetta Grigsby, Allyson Hamlin, Eleni Kotsis, Trigger McNair, Tia Watkins |
| 2016 | Kenyetta Grigsby, Allyson Hamlin, Eleni Kotsis, Trigger McNair, Tia Watkins |
| 2017 | Kathryn Blais, Safi Mojidi, Tia Watkins, Kentrina Wilson |
| 2018 | Eleni Kotsis, Trigger McNair, Tia Watkins, Becky Worsham |
